head to head
Neither is simply harder - they are hard in different places. Fallout 2 demands more variance; Portal demands more execution.

Optimization · Pure Optimization
A post-nuclear RPG expanded in scope where tagged builds and Gifted-trait optimization dominate.

Optimization · Pure Optimization
The portal-gun puzzle game whose solutions are everything.
Fallout 2 leans Optimization (Pure Optimization); Portal leans Optimization (Pure Optimization).
Portal leans clearly harder on execution.
Fallout 2
Turn-based AP system makes twitch entirely irrelevant
Portal
Portal placement timing modest.
Fallout 2 leans a little harder on reads, though the gap is small.
Fallout 2
All tribal and Enclave enemies run fixed scripted combat routines
Portal
No adversary modeling player.
Fallout 2 leans clearly harder on variance.
Fallout 2
Hidden special encounters and timed events create significant unknown-information space
Portal
Deterministic chambers; no randomness.
Fallout 2 leans a little harder on optimization, though the gap is small.
Fallout 2
SPECIAL and skill tagging with Gifted trait produce well-known dominant build strategies
Portal
Pure puzzle-solving optimization.
A matching score does not mean a matching test. Two games can both sit at 10 on execution and demand completely different things of you - which is why the reasoning above matters more than the number beside it.