head to head
Neither is simply harder - they are hard in different places. Pokémon White Version demands more variance; Portal 2 demands more execution.

Optimization · Pure Optimization
Solvable team-building progression through an all-new fixed roster.

Optimization · Pure Optimization
A first-person puzzle game where seeing the solution is the whole skill.
Pokémon White Version leans Optimization (Pure Optimization); Portal 2 leans Optimization (Pure Optimization).
Portal 2 leans clearly harder on execution.
Pokémon White Version
Menu battles need no dexterity
Portal 2
Portal placement requires some precision but timing is lenient.
Pokémon White Version leans a little harder on reads, though the gap is small.
Pokémon White Version
Campaign trainers are scripted; competitive play is separate
Portal 2
No opponent; puzzles are static.
Pokémon White Version leans clearly harder on variance.
Pokémon White Version
All-new Pokémon are unknowns until the dex fills
Portal 2
Puzzles are deterministic with no randomness.
Portal 2 leans a little harder on optimization, though the gap is small.
Pokémon White Version
Fresh type matchups still reduce to solvable team building
Portal 2
Solving the puzzle's logic IS the entire game.
A matching score does not mean a matching test. Two games can both sit at 10 on execution and demand completely different things of you - which is why the reasoning above matters more than the number beside it.