head to head
Neither is simply harder - they are hard in different places. Portal 2 demands more optimization; The Sims demands more variance.

Optimization · Pure Optimization
A first-person puzzle game where seeing the solution is the whole skill.

Optimization · Pure Optimization
An open-ended needs-and-money system that rewards efficient scheduling.
Portal 2 leans Optimization (Pure Optimization); The Sims leans Optimization (Pure Optimization).
Portal 2 leans clearly harder on execution.
Portal 2
Portal placement requires some precision but timing is lenient.
The Sims
Clicking menus has no physical ceiling
Same score on reads - which means the number cannot separate them. The difference is in what each one asks of you.
Portal 2
No opponent; puzzles are static.
The Sims
Sims run need-driven scripts, not minds
The Sims leans clearly harder on variance.
Portal 2
Puzzles are deterministic with no randomness.
The Sims
Event rolls add flavour, all quickly mapped
Portal 2 leans clearly harder on optimization.
Portal 2
Solving the puzzle's logic IS the entire game.
The Sims
Need scheduling, career grinding and money loops are solvable
A matching score does not mean a matching test. Two games can both sit at 10 on execution and demand completely different things of you - which is why the reasoning above matters more than the number beside it.