head to head
Neither is simply harder - they are hard in different places. Portal demands more execution; Riven demands more variance.

Optimization · Pure Optimization
The portal-gun puzzle game whose solutions are everything.

Optimization · Pure Optimization
The Myst sequel: a slow, wordless puzzle adventure solved by observing an alien world's internal logic.
Portal leans Optimization (Pure Optimization); Riven leans Optimization (Pure Optimization).
Portal leans clearly harder on execution.
Portal
Portal placement timing modest.
Riven
Point-and-click; no dexterity required at all
Same score on reads - which means the number cannot separate them. The difference is in what each one asks of you.
Portal
No adversary modeling player.
Riven
No opponent of any kind
Riven leans clearly harder on variance.
Portal
Deterministic chambers; no randomness.
Riven
Information is hidden only until you observe it
Riven leans a little harder on optimization, though the gap is small.
Portal
Pure puzzle-solving optimization.
Riven
Deciphering the world's logic is one giant solvable puzzle
A matching score does not mean a matching test. Two games can both sit at 10 on execution and demand completely different things of you - which is why the reasoning above matters more than the number beside it.