head to head
Neither is simply harder - they are hard in different places. Portal demands more execution; RollerCoaster Tycoon 2 demands more variance.

Optimization · Pure Optimization
The portal-gun puzzle game whose solutions are everything.

Optimization · Pure Optimization
A park management puzzle where understanding the guest happiness formula lets you solve each scenario optimally.
Portal leans Optimization (Pure Optimization); RollerCoaster Tycoon 2 leans Optimization (Pure Optimization).
Portal leans clearly harder on execution.
Portal
Portal placement timing modest.
RollerCoaster Tycoon 2
Track building is grid-based with modest placement precision demands
Same score on reads - which means the number cannot separate them. The difference is in what each one asks of you.
Portal
No adversary modeling player.
RollerCoaster Tycoon 2
Guest behaviour follows fixed preference scripts
RollerCoaster Tycoon 2 leans clearly harder on variance.
Portal
Deterministic chambers; no randomness.
RollerCoaster Tycoon 2
Very little randomness once ride stats are understood
RollerCoaster Tycoon 2 leans a little harder on optimization, though the gap is small.
Portal
Pure puzzle-solving optimization.
RollerCoaster Tycoon 2
Pricing, ride stats, and park layout are near-perfectly solvable
A matching score does not mean a matching test. Two games can both sit at 10 on execution and demand completely different things of you - which is why the reasoning above matters more than the number beside it.