head to head
Neither is simply harder - they are hard in different places. Portal demands more optimization; The Fall demands more variance.

Optimization · Pure Optimization
The portal-gun puzzle game whose solutions are everything.

Optimization · Pure Optimization
Reasoning through fixed adventure-logic puzzles inside a sci-fi story.
Portal leans Optimization (Pure Optimization); The Fall leans Optimization (Pure Optimization).
Portal leans clearly harder on execution.
Portal
Portal placement timing modest.
The Fall
Light combat and platforming pose little physical test
Same score on reads - which means the number cannot separate them. The difference is in what each one asks of you.
Portal
No adversary modeling player.
The Fall
Story AI characters are fully scripted
The Fall leans clearly harder on variance.
Portal
Deterministic chambers; no randomness.
The Fall
Puzzle solutions are hidden until reasoned out
Portal leans clearly harder on optimization.
Portal
Pure puzzle-solving optimization.
The Fall
Adventure-logic puzzles each have one intended answer
A matching score does not mean a matching test. Two games can both sit at 10 on execution and demand completely different things of you - which is why the reasoning above matters more than the number beside it.