head to head
Neither is simply harder - they are hard in different places. Civilization V demands more variance; Portal demands more execution.

Optimization · Pure Optimization
Optimizing city placement, social policies, and victory routing under randomized map unknowns.

Optimization · Pure Optimization
The portal-gun puzzle game whose solutions are everything.
Civilization V leans Optimization (Pure Optimization); Portal leans Optimization (Pure Optimization).
Portal leans clearly harder on execution.
Civilization V
UI actions need no precision; speed is not a factor
Portal
Portal placement timing modest.
Civilization V leans clearly harder on reads.
Civilization V
AI follows scripted personalities, not genuine player modelling
Portal
No adversary modeling player.
Civilization V leans clearly harder on variance.
Civilization V
Random starts, barbarian spawns, and goody huts create hidden unknowns
Portal
Deterministic chambers; no randomness.
Civilization V leans a little harder on optimization, though the gap is small.
Civilization V
Hex placement, social policies, and victory routing are fully solvable
Portal
Pure puzzle-solving optimization.
A matching score does not mean a matching test. Two games can both sit at 10 on execution and demand completely different things of you - which is why the reasoning above matters more than the number beside it.