head to head
Neither is simply harder - they are hard in different places. Portal demands more execution; Sid Meier's Alpha Centauri demands more variance.

Optimization · Pure Optimization
The portal-gun puzzle game whose solutions are everything.

Optimization · Pure Optimization
Mastering interlocking social engineering and tech-tree systems on a programmable alien world.
Portal leans Optimization (Pure Optimization); Sid Meier's Alpha Centauri leans Optimization (Pure Optimization).
Portal leans clearly harder on execution.
Portal
Portal placement timing modest.
Sid Meier's Alpha Centauri
Turn-based; no twitch element at all
Sid Meier's Alpha Centauri leans clearly harder on reads.
Portal
No adversary modeling player.
Sid Meier's Alpha Centauri
AI faction leaders follow fixed personality scripts
Sid Meier's Alpha Centauri leans clearly harder on variance.
Portal
Deterministic chambers; no randomness.
Sid Meier's Alpha Centauri
Xenofungus and psi combat add some irreducible randomness
Sid Meier's Alpha Centauri leans clearly harder on optimization.
Portal
Pure puzzle-solving optimization.
Sid Meier's Alpha Centauri
Tech tree, social engineering, and base placement are essentially solvable
A matching score does not mean a matching test. Two games can both sit at 10 on execution and demand completely different things of you - which is why the reasoning above matters more than the number beside it.